Organic Compounds Containing Halogens Question 142

Question: Chloropicrin is obtained by the reaction of

[CBSE PMT 2004]

Options:

A) Chlorine on picric acid

B) Nitric acid on chloroform

C) Steam on carbon tetrachloride

D) Nitric acid on chlorobenzene

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Answer:

Correct Answer: B

Solution:

When chloroform is treated with concentrated nitric acid, its hydrogen is replaced by nitro group. $ CHCl_3+HONO_2\to \underset{chloropicrin}{\mathop{CNO_2Cl_3}}+H_2O $