Organic Compounds Containing Halogens Question 152

Question: When but -3-en -2- ol reacts with aq. HBr, the product formed is

[DCE 2001]

Options:

A) 3 - bromobut - 1- ene

B) 1 - bromobut - 2- ene

C) A mixture of both a and b

D) 2 - bromobut - 2 - ene

Show Answer

Answer:

Correct Answer: C

Solution:

$ H_2\overset{\oplus }{\mathop{C}}-CH=CH-CH_3]\xrightarrow{B{r^{}}} $

$ \underset{\text{3 Bromobut-1-ene}}{\mathop{H_2C=CH-\overset{Br}{\mathop{\overset{|}{\mathop{C}}H}}-CH_3}}+\underset{\text{1 Bromo but-2-ene}}{\mathop{Br-CH_2-CH=CH-CH_3}} $