Organic Compounds Containing Halogens Question 196

Question: Which one of the following reagents is not suitable for the elimination reaction-

Options:

A) NaI/acetone

B) NaOEt/EtOH

C) $ NaOH/H_2O $

D) $ NaOH/H_2O-EtOH $

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Alkyl chloride or bromide undergo substitution and get converted to an alkyl iodide on treatment with a solution of sodium iodide in acetone, e.g. $ CH_3CH_2CH_2Br+NaI\xrightarrow{acetone} $

$ CH_3CH_2CH_2I+NaBr $ This reaction is also known as Finkelstein Reaction.