Organic Compounds Containing Halogens Question 27

Question: In fire extinguisher, pyrene is

[DPMT 1985]

Options:

A) $ CO_2 $

B) $ CCl_4 $

C) $ CS_2 $

D) $ CHCl_3 $

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Answer:

Correct Answer: B

Solution:

$ CCl_4 $ is stable to red heat. Its vapours are highly non-inflammable i.e. do not catch fire. It is because of this property $ CCl_4 $ is used as a fire extinguisher.

But now a days its use as a fire extinguisher is restricted because with water vaporous. It forms highly poisonous phosgene gas $ CCl_4+H_2O\to \underset{Phosgene}{\mathop{COCl_2}}+2HCl $