Organic Compounds Containing Halogens Question 35

Question: Wurtz reaction of methyl iodide yields an organic compound X. Which one of the following reactions also yields X

[EAMCET 2003]

Options:

A) $ C_2H_5Cl+Mg\xrightarrow{dryether} $

B) $ C_2H_5Cl+LiAlH_4\xrightarrow{{}} $

C) $ C_2H_5Cl+C_2H_5ONa\xrightarrow{{}} $

D) $ CHCl_3\underset{\Delta }{\mathop{\xrightarrow{Ag\ powder}}} $

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Answer:

Correct Answer: B

Solution:

Wurtz reaction gives ethane $ 2CH_3I+2Na\underset{ether}{\mathop{\xrightarrow{dry}}}C_2H_6+2NaI $

Similarly $ C_2H_5Cl $ reduced by $ LiAlH_4 $ to give ethane $ C_2H_5Cl+2H\xrightarrow{LiAlH_4}C_2H_6+HCl $