Organic Compounds Containing Halogens Question 43

Question: In methyl alcohol solution, bromine reacts with ethylene to yield $ BrCH_2CH_2OCH_3 $ in addition to 1, 2-dibromoethane because

[Pb. PMT 1998]

Options:

A) The ion formed initially may react with $ B{r^{-}} $ or $ CH_3OH $

B) The methyl alcohol solvates the bromine

C) The reaction follows Markownikoff’s rule

D) This is a free-radical mechanism

Show Answer

Answer:

Correct Answer: A

Solution:

$ CH_2=CH_2+Br_2\xrightarrow{CH_3OH} $

$ \underset{Br}{\mathop{\underset{|}{\mathop{C}}H_2-}}\underset{Br}{\mathop{\underset{|}{\mathop{C}}H_2+}}Br-CH_2-CH_2-O-CH_3 $