Organic Compounds Containing Halogens Question 58

Question: Which compound does not form iodoform with alkali and iodine

[IIT-JEE 1985]

Options:

A) Acetone

B) Ethanol

C) Diethyl ketone

D) Isopropyl alcohol

Show Answer

Answer:

Correct Answer: C

Solution:

$ CH_3CH_2-CO-CH_2-CH_3\xrightarrow{NaOH/I_2}\text{No yellow ppt} $

$ . \begin{matrix} CH_3COCH_3\xrightarrow{NaOH/I_2}CHI_3 \\ C_2H_5OH\xrightarrow{NaOH/I_2}CHI_3 \\ CH_3-\underset{OH}{\mathop{\underset{|}{\mathop{CH}}}}-CH_3\xrightarrow{NaOH/I_2}CHI_3 \\ \end{matrix} yellowppt. $