Organic Compounds Containing Halogens Question 59

Question: Which compound gives yellow ppt. with iodine and alkali

[IIT-JEE 1984]

Options:

A) 2-hydroxypropane

B) Acetophenone

C) Acetone

D) Acetamide

Show Answer

Answer:

Correct Answer: B

Solution:

Methyl acetate and Acetamide will not give a yellow precipitate. But 2-Hydroxypropane and Acetophenone will not give a yellow precipitate.

$ \underset{Acetophenone}{\mathop{CH_3-\underset{O}{\mathop{\underset{||}{\mathop{C}}}}C_6H_5}}\underset{I_2}{\mathop{\xrightarrow{NaOH}}}\underset{\text{Yellow ppt}\text{.}}{\mathop{CHI_3}}+ C_6H_5CO_2Na$



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