Organic Compounds Containing Halogens Question 8

Question: Which of the following is correct-

Options:

A) A on reaction with aq. KOH gives $ HOCH_2CH_2COOK $

B) B can be resolved into d- and l-forms

C) Both [a] and [b]

D) Neither [a] nor [b]

Show Answer

Answer:

Correct Answer: C

Solution:

[c] The compound A is $ Cl_3C.CH_2.CH_2Cl\xrightarrow{aq.KoH} $

$ {{( OH )}_3}C.CH_2CH_2OH $

$ \xrightarrow{-2H_2O}HOCH_2.CH_2COOK. $ The compounds B is $ Cl_3C-\underset{Br}{\mathop{\underset{|}{\overset{*}{\mathop{C}}}}}H-CH_2Br $ has chiral centre and can be resolved into d- and l- form.