Organic Compounds Containing Halogens Question 88

Question: The odd decomposition of carbon chlorine bond form

[UPSEAT 1999]

Options:

A) Two free ions

B) Two-carbanium ion

C) Two carbanion

D) A cation and an anion

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Answer:

Correct Answer: D

Solution:

$ R-CH_2-Cl\xrightarrow{\text{Heterolytic bond fission}}\underset{cation}{\mathop{RCH_2^{\oplus }}}+\underset{anion}{\mathop{C{l^{}}}} $ Cl is more electronegative than C by which it form anion and hydrocarbon form cation.