P Block Elements Question 554

$ XeO_4 $ molecule is tetrahedral having: 4 sigma bonds and no lone pairs on the central atom.

Options:

A) Two $ p\pi -d\pi $ bonds

B) One $ p\pi -d\pi $ bonds

C) Four $ p\pi -d\pi $ bonds

D) Three $ p\pi -d\pi $ bonds

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Answer:

Correct Answer: C

Solution:

Xenon undergoes $ sp^{3} $ hybridization. In the fourth excited state xenon atom, there are 8 unpaired electrons. One s and three p orbitals undergo $ sp^{3} $ hybridization. Four $ sp^{3} $ hybrid orbitals form four $ \sigma $ bonds with oxygen atoms. They are $ \sigma sp^{3}-p $ . Four $ p\pi -d\pi $ bonds are also formed with oxygen atoms by the unpaired electrons.



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