Polymers Question 108

Question: Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation.

(I) $ CH_2=CH-C_6H_4(NO_2) $ (II) $ CH_2=CH-C_6H_4(CH_3) $ (III) $ CH_2=CH-C_6H_4(OCH_3) $

Options:

A) I > II > III

B) II > I > III

C) III > II > I

D) I > III > II

Show Answer

Answer:

Correct Answer: C

Solution:

[c] More stable is carbocation more is ability to undergo cationic polymerization. +I and +R nature of $ -OCH_3 $ stabilizes carbocation.