Polymers Question 26

Question: In the natural rubber -Caoutchouc-, the isoprene units are joined by

Options:

A) Head-to-head

B) Tail-to-tail

C) Head-to-tail

D) All of these

Show Answer

Answer:

Correct Answer: C

Solution:

$ \overset{Head}{\mathop{CH_2}}=\underset{CH_3}{\mathop{\underset{|}{\mathop{C-}}}}CH=\overset{Tail}{\mathop{CH_2}}+\overset{Head}{\mathop{CH_2}}=\underset{CH_3}{\mathop{\underset{|}{\mathop{C-CH}}}}=\overset{Tail}{\mathop{CH_2}}\to $

$ {{(-CH_2-\underset{CH_2}{\mathop{\underset{|}{\mathop{C=}}CH}}-CH_2-CH_2-\underset{CH_3}{\mathop{\underset{|}{\mathop{C=}}CH}}-CH_2-)} _{n}} $ From steric effects, the polymer formed has head to tail configuration.