Polymers Question 27

Question: The degree of crystallinity of which of the following is highest

Options:

A) Atactic polyvinylchloride

B) Isotactic polyvinylchloride

C) Syndiotactic polyvinylchloride

D) All of these

Show Answer

Answer:

Correct Answer: C

Solution:

Syndiotactic polyvinylchloride $ ( -CH_2-\underset{Cl}{\mathop{\underset{|}{\mathop{CH}}}}-CH_2-\overset{Cl}{\mathop{\overset{|}{\mathop{CH}}}}-CH_2-\underset{Cl}{\mathop{\underset{|}{\mathop{CH}}}}-CH_2-\overset{Cl}{\mathop{\overset{|}{\mathop{CH}}}} . $

$ -{{. CH_2-\underset{Cl}{\mathop{\underset{|}{\mathop{CH}}-}} )} _{n}} $ In this arrangement the chlorine atoms are alternately arranged. The polymer is stereoregular and has high crystallinity.