Polymers Question 28

Question: When condensation product of hexamethylenediamine and adipic acid is heated to $ 553K(80^{o}C) $ in an atmosphere of nitrogen for about 4-5 hours, the product obtained is

[DCE 2002; MHCET 2004]

Options:

A) Solid polymer of nylon 66

B) Liquid polymer of nylon 66

C) Gaseous polymer of nylon 66

D) Liquid polymer of nylon 6

Show Answer

Answer:

Correct Answer: B

Solution:

The condensation polymerisation of hexamethylene diamine and adipic acid is done in solution form by interface technique. In this liquid nylon polymer is obtained. $ n.H_2N-{{(CH_2)}_6}-NH_2 $

$ nHOOC-{{(CH_2)}_4}-COOH\underset{-nH_2O}{\mathop{\xrightarrow{Polymerisation}}} $

$ {{[-HN-(CH_2)_6-\underset{Nylon}{\mathop{NHCO}}-(CH_2)_4-CO-]}_n} $