Polymers Question 56

Question: What is not true regarding free radical polymerisation of propene-

Options:

A) Without proper control, atactic polypropylene is produced

B) During polymerization, a secondary free radical is produced in every step

C) Use of Ziegler-Natta catalyst results in isotactic polypropylene

D) During polymerization, a linear, unbranched, crystalline polymer is usually obtained

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Answer:

Correct Answer: D

Solution:

[d] Chain branching always takes place when an alkene undergoes free radical polymerization. This is due to the abstraction of some H-radicals form the growing polymer chain.