Purification And Characterisation Of Organic Compounds Question 145

Question: When $ CuSO_4 $ is electrolysed using platinum electrodes,

Options:

A) copper is liberated at cathode, sulphur at anode

B) copper is liberated at cathode, oxygen at anode

C) sulphur is liberated at cathode; oxygen anode

D) oxygen is liberated at cathode, copper at anode

Show Answer

Answer:

Correct Answer: B

Solution:

[b] $ CuSO_4\rightarrow C{{u}^{2+}}+SO_4^{2-} $

$ H_2O\rightarrow {{H}^{+}}+O{{H}^{-}} $ At cathode: $ C{{u}^{2+}}+2{{e}^{-}}\to Cu $ At anode: $ 4O{{H}^{-}}\to 2H_2O+O_2+4{{e}^{-}}~ $