Purification And Characterisation Of Organic Compounds Question 175

Question: Pb and Sn are extracted from their chief ore by

[IIT-JEE Screening 2004]

Options:

A) Carbon reduction and self-reduction.

B) Self reduction and carbon reduction.

C) Electrolysis and self-reduction.

D) Self-reduction and electrolysis.

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Answer:

Correct Answer: B

Solution:

$ PbO $ & $ PbSO_4 $ get reduced by PbS itself which is already present in mixture so because the reduction took place by mixture itself, hence is known as self reduction.

$ 2PbO+PbS\xrightarrow{\Delta }3Pb+SO_2\uparrow $

$ PbSO_4+PbS\xrightarrow{\Delta }2Pb+2SO_2\uparrow $