Purification And Characterisation Of Organic Compounds Question 9

Question: In the electrolysis of alumina to obtain aluminiumb metal, cryolite is added mainly to

Options:

A) lower the melting point of alumina

B) dissolve alumina in molten cryolite

C) remove the impurities of alumina

D) increase the electrical conductivity

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Fused alumina $ (Al_2O_3) $ is a bad conductor of electricity.

Therefore, cryolite $ (Na_3AlF_6) $ and fluorspar $ (CaF_2) $ are added to purified alumina which not only make alumina a good conductor of electricity but also reduce the melting point of the mixture to around 1140 K.