Purification And Characterisation Of Organic Compounds Question 96

Question: Which one of the following is manufactured by the electrolysis of fused sodium chloride

[CPMT 1979, 83, 91]

Options:

A) $ NaOH $

B) $ NaClO $

C) $ Na $

D) $ NaClO_3 $

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Answer:

Correct Answer: C

Solution:

$ \underset{(fused)}{\mathop{2NaCl}}\to 2N{{a}^{+}}+2C{{l}^{-}} $
Anode: $ 2C{{l}^{-}}\to 2{{e}^{-}}+Cl_2 $ (oxidation)

Cathode: $ 2N{{a}^{+}}+2{{e}^{-}}\to 2Na $ - (reduction)