Redox Reactions And Electrochemistry Question 18

Question: An electrochemical cell is set up as follows : Pt , H2 ( 1 atm) | HCl (0.1M) // Acetic Acid (0.1 M ) | H2 ,Pt (1 atm) . E.M.F of the cell will not be zero because : [CBSE PMT 1995]

Options:

A) The $ pH $ of 0.1 M HCl and 0.1 M acetic acid is not the same

B) Acids used in two compartments are different

C) E.M.F. of a cell depends on the molarities of acids used

D) The temperature is constant

Show Answer

Answer:

Correct Answer: A

Solution:

The pH of 0.1 M $ HCl $ and 0.1 M acetic acid is not the same, because $ HCl $ is a strong acid so its pH is less and $ CH_3COOH $ is a weak acid, so its pH is more.