Redox Reactions And Electrochemistry Question 477

Question: The ionic conductivity of $ B{a^{2+}} $ and $ C{l^{-}} $ at infinite dilution are 127 and 76 $ oh{m^{-1}} $ $ cm^{2}e{q^{-1}} $ respectively. The equivalent conductivity of $ BaCl_2 $ at infinity dilution (in $ oh{m^{-1}},Cm^{2}e{q^{-1}} $ ) would be:

Options:

A) 203

B) 279

C) 101.5

D) 139.5

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Equivalent conductivity of $ BaCl_2 $ $ \Lambda _m^{\infty }(BaCl_2)=\lambda _m^{\infty }(B{a^{2+}})+2\lambda _m^{\infty }(C{l^{-}}) $ $ =127+2\times 76=279oh{m^{-1}}cm^{2}e{q^{-1}}. $



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