Redox Reactions And Electrochemistry Question 516

Question: For a cell reaction involving two electron change, the standard EMF of the cell is 0.295 V at $ 2{}^\circ C $ . The equilibrium constant of the reaction at $ 25{}^\circ C $ will be:

Options:

A) $ 29.5\times {10^{-2}} $

B) 10

C) $ 1\times 10^{10} $

D) $ 2.95\times {10^{-10}} $

Show Answer

Answer:

Correct Answer: C

Solution:

[c] Using the relation, $ E{{{}^\circ } _{cell}}=\frac{2.303RT}{nF}\log K _{eq}=\frac{0.0591}{n}\log K _{eq} $

$ \therefore 0.295V=\frac{0.0591}{2}\log K_{eq} $ Or $ \log K_{eq}=\frac{2\times 0.295}{0.0591}=10 $ Or $ K_{eq}=1\times 10^{10} $



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