Redox Reactions And Electrochemistry Question 671

Question: Salts of A (atomic weight: 7), B (atomic weight: 27), and C (atomic weight: 48) were electrolyzed under identical condition using the same quantity of electricity. It was found that when 2.1 got A was deposited, the weights of B and C deposited were 2.7 and 7.2 g, respectively. The valencies of A, B and C, respectively are:

Options:

A) 3, 1 and 2

B) 1, 3 and 2

C) 3, 1 and 3

D) 2, 3 and 2

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Eq. of A = Eq. of B = Eq. of C $ \frac{2.1}{7/n_1}=\frac{2.7}{27/n_2}=\frac{7.2}{48/n_3} $ $ 0.3n_1=0.1n_2=0.15n_3 $

$ \therefore $ $ n_1=\frac{n_2}{3}=\frac{n_3}{2}=( n_1,n_2,n_3 ) $ are integers.



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