Redox Reactions And Electrochemistry Question 672

Question: The temperature coefficient of a cell whose operation is based on the reaction

$ Pb(s)+HgCl_2(aq)\xrightarrow{{}}PbCl_2(aq)+Hg(l) $ $ {{( \frac{dE}{dT} )}_{p}}=1.5\times {10^{-4}}V/K,at,298K $ The change in entropy (in J/K mol) during the operation is:

Options:

A) 8627

B) 57.9

C) 28.95

D) 14.475

Show Answer

Answer:

Correct Answer: C

Solution:

[c] $ \Delta S=nF{{( \frac{dE}{dT} )}_{P}}\Rightarrow 2\times 96500\times 1.5\times {10^{-4}} $
$ \Rightarrow $ $ 28.95,J/K,mol $



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