Redox Reactions And Electrochemistry Question 699
Question: Which of the following is not a disproportionate reaction-
Options:
A) $ 4KClO_3\xrightarrow[{}]{{}}3KClO_4+KCl $
B) $ 2C{{u}^{+}}\xrightarrow[{}]{{}}C{{u}^{2+}}+Cu $
C) $ 5{{X}^{-}}+XO_3^{-}+6{{H}^{+}}\xrightarrow[{}]{{}}3X_2+3H_2O $
D) $ 4P+3NaOH+3H_2O\to $ $ PH_3+3NaH_2PO_2 $
Show Answer
Answer:
Correct Answer: C
Solution:
[c] The change in oxidation numbers are
[a]  $ Cl:+,5\to +7 $  and - 1     
[b]  $ Cu:+1\to +2 $  and 0
[c]  $ X:-1\to 0 $            
[d]  $ P:0\to -3 $  and + 1
In [a], [b] and [d], a single oxidation number (of the reactant atom) undergoes a simultaneous increase and decrease, but in [c], two different oxidation numbers of an atom in the reactants are not involved.
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