Redox Reactions And Electrochemistry Question 745

The standard electrode potential $ (E^{o}) $ for $ Cl_2/Cl^{-} $ and $ Cl^{-}/\frac{1}{2}Cl_2 $ respectively are $ 1.36,V $ and $ -1.36,V $ . The $ E^{o} $ value for $ Cl_2/Cl^{-} $ will be [KCET 1996]

Options:

A) $ -0.42,V $

B) $ -,2.20,V $

C) $ 0.52,V $

D) $ 1.04,V $

Show Answer

Answer:

Correct Answer: A

Solution:

$ Cl^{-}\to \frac{1}{2}Cl_2+{e^{-}},,E^{o}=-1.36V $ $ Cl^{-}\to {C^{-}},,E^{o}=0.94V $ adding the two equations, we get $ Cl^{-}\to \frac{1}{2}Cl_2,,E^{o}=0.94-1.36=-0.42,V $ .



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