S Block Elements Question 124

Question: NaOH is prepared by the method

[AFMC 2005]

Options:

A) Down’s cell

B) Castner cell

C) Solvay process

D) Castner Kellner cell

Show Answer

Answer:

Correct Answer: D

Solution:

The cell involves the following reaction, $ NaCl $ ⇌ $ N{{a}^{+}}+C{{l}^{-}} $ At anode : $ 2C{{l}^{-}}\to 2Cl+2e\to Cl_2 $ At cathode : $ N{{a}^{+}}+e\to Na $

$ Na+Hg\to $ amalgam At anode : $ Na- $ amalgam $ \to N{{a}^{+}}+Hg+e $ At cathode : $ 2H_2O+2e\to H_2\uparrow +2O{{H}^{-}} $