S Block Elements Question 139

Question: Setting of plaster of paris is

[MP PMT 1985; CPMT 1989]

Options:

A) Oxidation with atmospheric oxygen

B) Combination with atmospheric $ CO_2 $

C) Dehydration

D) Hydration to yield another hydrate

Show Answer

Answer:

Correct Answer: D

Solution:

Setting of plaster of paris is exothermic process $ CaSO_4.\frac{1}{2}H_2O\xrightarrow{H_2O}\underset{\text{Orthorhombic }}{\mathop{CaSO_4.2H_2O}} $

$ \xrightarrow{Hardening}\underset{\begin{smallmatrix} \text{Mono orthorhombic } \\ Gypsum \end{smallmatrix}}{\mathop{CaSO_4.2H_2O}} $ The setting is due to formation of another hydrate