S Block Elements Question 199

Question: A sodium salt on treatment with $ MgCl_2 $ gives white precipitate only on heating. The anion of the sodium salt is

[IIT JEE Screening 2004]

Options:

A) $ HCO_3^{-} $

B) $ CO_3^{2-} $

C) $ NO_3^{-} $

D) $ SO_4^{2-} $

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Answer:

Correct Answer: A

Solution:

$ MgCl_2+2NaHCO_3\to Mg{{(HCO_3)}_2}(aq)+2NaCl $

$ Mg{{(HCO_3)}_2}(aq)\xrightarrow{\Delta }\underset{\text{(White ppt}\text{.)}}{\mathop{MgCO_3}}\downarrow +H_2O+CO_2\uparrow $