S Block Elements Question 253

Question: mongst $ LiCl,\ RbCl,\ BeCl_2 $ and $ MgCl_2 $ the compounds with the greatest and least ionic character respectively are

[Pb. CET 2004]

Options:

A) $ LiCl $ and $ RbCl $

B) $ MgCl_2 $ and $ BeCl_2 $

C) $ RbCl $ and $ BeCl_2 $

D) $ RbCl $ and $ MgCl_2 $

Show Answer

Answer:

Correct Answer: C

Solution:

According to Fajan’s rule RbCl has greatest ionic character due to large ionic size of $ R{{b}^{+}} $ ion. $ BeCl_2 $ has least ionic (Maximum covalent) due to small size of $ B{{e}^{+2}} $ ion which has highly polarising.