S Block Elements Question 292

Question: The atomic radii of alkali metals (M) lie in the order $ Li<Na<K<Rb $ but the radii of $ {{M}^{+}} $ ions in aqueous solution lie in the reverse order $ L{{i}^{+}}>N{{a}^{+}}>{{K}^{+}}>R{{b}^{+}} $ . What is the reason for this reverse order (on going from $ Li $ to $ Rb) $ -

[MP PMT 1997]

Options:

A) Gradual increase in ionisation energy

B) Increasing weakness of the metallic bond

C) Increasing electropositive character

D) Decreasing degree of hydration

Show Answer

Answer:

Correct Answer: D

Solution:

Smaller the atomic size tendency of hydration is more as the size increases tendency for hydration also decreases.