S Block Elements Question 87

Question: Incorrect statement is:

Options:

A) $ NaHCO_3 $ and $ KHCO_3 $ have same crystal structure

B) On heating $ LiNO_3 $ decomposes into $ Li_2O $ and $ NO_2 $

C) Among alkali metals, $ Li $ metal impart red colour to flame

D) $ Li_2SO_4 $ does not form alum

Show Answer

Answer:

Correct Answer: A

Solution:

[a] The crystal structures of $ NaHCO_3 $ and $ KHCO_3 $ both show hydrogen bonding but are different.

In $ NaHCO_3, $ the $ HCO_3^{-} $ ions are linked into an infinite chain, while in $ KHCO_3, $ a dimeric anion is formed.