Solid State Question 10

Question: A solid has a structure in which ‘W’ atoms are located at the comers of a cubic lattice ‘O’ atoms at the centre of edges and Na atoms at the centre of the cube. The formula for the compound is

Options:

A) $ Na_2WO_3 $

B) $ Na_2WO_2 $

C) $ NaWO_2 $

D) $ NaWO_3 $

Show Answer

Answer:

Correct Answer: D

Solution:

[d] In a unit cell, W atoms at the corner $ =\frac{1}{8}\times 8=1 $ O-atoms at the centre of edges $ ~=\frac{1}{4}\times 12=3 $ Na-atoms at the centre of the cube = 1 $ W:O:Na=1:3:1 $ Hence, formula $ =NaWO_3 $



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