Solid State Question 240

Question: Potassium has a $ bcc $ structure with nearest neighbour distance $ 4.52{AA}. $ Its atomic weight is 39. Its density (in $ kg{{m}^{-3}} $ ) will be

[AIIMS 1991]

Options:

A) 454

B) 804

C) 852

D) 908

Show Answer

Answer:

Correct Answer: D

Solution:

For bcc, $ d=\frac{\sqrt{3}}{2}a $ or $ a=\frac{2d}{\sqrt{3}}=\frac{2\times 4.52}{1.732}=5.219\mathring{A}=522pm $

$ \rho =\frac{Z\times M}{a^{3}\times N_0\times {{10}^{-30}}} $

$ =\frac{2\times 39}{{{(522)}^{3}}\times (6.023\times 10^{23})\times {{10}^{-30}}} $

$ =0.91g/cm^{3}=910kg{{m}^{-3}} $