Solid State Question 268

Question: Which of the following statements are correct in context of point defects in a crystal-

Options:

A) AgCl has anion Frenkel defect and $ CaF_2 $ has Schottky defects

B) AgCl has cation Frenkel defects and $ CaF_2 $ has anion Frenkel defects

C) AgCl and $ CaF_2 $ have anion Frenkel defects

D) AgCl and $ CaF_2 $ have Schottky defects

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Since $ A{{g}^{+}} $ (cation) is smaller than $ C{{l}^{-}} $ (anion) and hence cation is present in voids. In $ CaF_2,C{{a}^{2+}} $ is smaller.