Solid State Question 303

Question: The edge length of unit cell of a metal having molecular weight 75 g/mol is $ 5\overset{{}^\circ }{\mathop{A}} $ which crystallizes in cubic lattice. If the density is 2g/cc then find the radius of metal atom. $ (N _{A}=6\times 10^{23}) $ . Give the answer in pm.

Options:

A) 217pm

B) 210pm

C) 220pm

D) 205pm

Show Answer

Answer:

Correct Answer: A

Solution:

[a] $ \rho =\frac{ZM}{N _{A}V} $

$ Z=\frac{\rho N _{A}V}{M}=\frac{2\times 6\times 10^{23}\times {{(5\times {{10}^{-8}})}^{3}}}{75} $ Z= 2, which represents bcc structure
$ \therefore ~r=\frac{\sqrt{3}}{4}a=\frac{\sqrt{3}}{4}\times 5=2.165\overset{{}^\circ }{\mathop{A}}=216.5pm $

$ \approx 217pm $