Solid State Question 60

Question: A molecule $ A_2B $ (Mwt. = 166.4) occupies triclinic lattice with a $ 5\overset{o}{\mathop{A}},b=8\overset{o}{\mathop{A}}, $ and $ c=4\overset{o}{\mathop{A}}. $ If the density of $ AB_2 $ is $ 5.2gc{{m}^{-3}} $ , the number of molecules present in one unit cell is

Options:

A) 2

B) 3

C) 4

D) 5

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Volume of unit cell $ =a\times b\times c $

$ =5\times {{10}^{-8}}\times 8\times {{10}^{-8}}\times 4\times {{10}^{-8}} $

$ =1.6\times {{10}^{-22}}cm^{3} $ Mass of unit cell $ =1.6\times {{10}^{-22}}\times 5.2 $

$ =8.32\times {{10}^{-22}}g $ Number of molecules in one unit cell $ =\frac{8.32\times {{10}^{-22}}}{166.4gmo{{l}^{-1}}}=3 $