Solid State Question 67

Question: The composition of sample of wustite is $ F{e _{0.93}}{O _{1.00}} $ . What percentage of the iron is present in the form of Fe (III)-

Options:

A) 14%

B) 15.05%

C) 17%

D) 29%

Show Answer

Answer:

Correct Answer: B

Solution:

[b] $ F{e _{0.93}}{O _{1.00}} $ Oxidation number of $ F{e _{0.93}} $ = + 2 (0.93 mol possess net + 2 charge)

Suppose x mol + 2 charge.

then 0.93 - x posses + 3 charge

Hence, $ x\times 2+3(0.93-x)=+2 $

$ x=0.79F{{e}^{2+}};F{{e}^{3+}}=0.14 $ $ F{{e}^{3+}}$%=$\frac{0.14}{0.93}\times 100=15.05% $