Solid State Question 78

Question: $ ZnO $ is white when cold and yellow when heated. It is due to the development of

Options:

A) Frenkel defect

B) Schottky defect

C) Metal excess defect

D) Metal deficiency defect

Show Answer

Answer:

Correct Answer: C

Solution:

[c] $ ZnO\xrightarrow{\Delta }Z{{n}^{2+}}+\frac{1}{2}O_2+2{{e}^{-}} $ The remaining $ Z{{n}^{2+}} $ ions occupy the interstitial voids of remaining crystal, thus causing metal excess defect.