Solid State Question 94

Question: A crystal is made of particles A and B. A forms fcc packing and B occupies all the octahedral voids. If all the particles along the plane as shown in the figure are removed, then the formula of the crystal would be:

Options:

A) $ AB $

B) $ A_5B_7 $

C) $ A_7B_5 $

D) none of these

Show Answer

Answer:

Correct Answer: A

Solution:

[a] Effective number of (particles removed $ =4\times \frac{1}{8}+2\times \frac{1}{2}=\frac{3}{2} $

Effective number of B particles removed $ =2\times \frac{1}{4}+1=\frac{3}{2} $ Effective number of B particles present in a unit cell $ =4-\frac{3}{2}=\frac{5}{2} $ A : B
$ \frac{5}{2} $ : $ \frac{5}{2} $ or $ 1:1 $