Solid State Question 98

Question: Lithium borohydride crystallizes in an orthorhombic system with 4 molecules per unit cell. The unit cell dimensions are $ a=6.8\overset{o}{\mathop{A}},b=4.4\overset{o}{\mathop{A}} $ and $ c=7.2\overset{o}{\mathop{A.}} $ If the molar mass is 21.76, then the density of crystals is:

Options:

A) $ 0.6708gc{{m}^{-2}} $

B) $ 1.6708gc{{m}^{-3}} $

C) $ 2.6708gc{{m}^{-3}} $

D) None of these.

Show Answer

Answer:

Correct Answer: A

Solution:

[a] $ d=\frac{ZM}{a^{3}N _{A}}= $

$ \frac{4\times 21.76}{6.8\times {{10}^{-8}}\times 4.4\times {{10}^{-8}}\times 7.2\times {{10}^{-8}}\times 6.023\times 10^{23}} $

$ =0.6708gc{{m}^{-2}} $