Atoms And Nuclei Question 23

Question: If the wavelength of the first line of the Balmer series of hydrogen is $ 6561\ {AA} $ , the wavelength of the second line of the series should be [CPMT 1984; DPMT 2004]

Options:

A) $ 13122\ {AA} $

B) $ 3280\ {AA} $

C) $ 4860\ {AA} $

D) $ 2187\ {AA} $

Show Answer

Answer:

Correct Answer: C

Solution:

The wavelength of spectral line in Balmer series is given by

$ \frac{1}{\lambda }=R,[ \frac{1}{2^{2}}-\frac{1}{n^{2}} ] $

For first line of Balmer series, n = 3 Þ $ \frac{1}{{\lambda_{1}}}=R,[ \frac{1}{2^{2}}-\frac{1}{3^{2}} ]=\frac{5R}{36} $ ;

For second line n = 4. Þ $ \frac{1}{{\lambda_{2}}}=R,[ \frac{1}{2^{2}}-\frac{1}{4^{2}} ]=\frac{3R}{16} $

$ \frac{{\lambda_{2}}}{{\lambda_{1}}}=\frac{20}{27}\Rightarrow {\lambda_{1}}=\frac{20}{27}\times 6561=4860,{\AA} $



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