Atomic Structure Result Question 12-1

12. The radius of the second Bohr orbit for hydrogen atom is (Planck’s constant $(h)=6.6262 \times 10^{-34} \mathrm{Js}$; mass of electron $=9.1091 \times 10^{-31} \mathrm{~kg} ;$ charge of electron $(e)=1.60210 \times 10^{-19} \mathrm{C}$; permitivity of vacuum $\left.\left(\epsilon_0\right)=8.854185 \times 10^{-12} \mathrm{~kg}^{-1} \mathrm{~m}^{-3} \mathrm{~A}^2\right)$

(2017 Main)

(a) $1.65 $ $Å$

(b) $4.76 $ $Å$

(c) $0.529 $ $Å$

(d) $2.12 $ $Å$

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Answer:

Correct Answer: 12. ( d )

Solution:

  1. Bohr radius $\left(r_n\right)=\epsilon_0 n^2 h^2$

$\begin{aligned} r_n & =\dfrac{n^2 h^2}{4 \pi^2 m e^2 k Z} \\ k & =\dfrac{1}{4 \pi \epsilon_0} \\ \therefore \quad r_n & =\dfrac{n^2 h^2 \epsilon_0}{\pi m e^2 Z}=n^2 \dfrac{a_0}{Z} \end{aligned}$

where, $m=$ mass of electron

$e=$ charge of electron

$h=$ Planck’s constant

$k=$ Coulomb constant

$r_n=\dfrac{n^2 \times 0.53}{Z} $ $Å$

Radius of $n^{\text {th }}$ Bohr orbit for $H$-atom $=0.53 n^2 $ $Å$ $\quad \quad [Z=1$ for $H$ -atom $]$

$\therefore \quad $ Radius of $2^{\text {nd }}$ Bohr orbit for $H$-atom $=0.53 \times(2)^2=2.12 $ $Å$