Atomic Structure Result Question 14

14. The energy of an electron in the first Bohr orbit of H-atom is $-13.6$ eV . The possible energy value(s) of the excited state(s) for electrons in Bohr orbits of hydrogen is (are)

(1988)

(a) $-3.4 $ eV

(b) $-4.2 $ eV

(c) $-6.8 $ eV

(d) $+6.8 $ eV

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Answer:

Correct Answer: 14. ( a )

Solution:

  1. Energy of electron in $H$-atom is determined by the expression:

$ E_n=-\dfrac{13.6}{n^2} \mathrm{eV} \quad \text { where, } n=1,2,3, \ldots . $

In excited states, $E_2=-\dfrac{13.6}{4}=-3.4 \mathrm{~eV}$

$ E_3=-\dfrac{13.6}{9}=-1.51 \mathrm{~eV} \text { etc. } $