Atomic Structure Result Question 4-1

4. The graph between $|\psi|^2$ and $r$ (radial distance) is shown below. This represents

(2019 Main, 10 April I)

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(a) $1s$ -orbital

(b) $2 p$-orbital

(c) $3s$-orbital

(d) $2 s$-orbital

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Answer:

Correct Answer: 4. ( d )

Solution:

  1. The graphs between $|\psi|^2$ and $r$ are radial density plots having ( $n-l-1$ ) number of radial nodes. For $1 \mathrm{s}, 2 \mathrm{s}, 3 \mathrm{s}$ and $2 p$-orbitals these are respectively.

For $2$s-orbital number of radial node $= 2-0-1= 1$

For $3$s-orbital number of radial node $= 3-0-1= 2$

For $2$p-orbital number of radial node $= 2-1-1= 0$

Thus, the given graph between $|\psi|^2$ and $r$ represents $2 s$-orbital.