Atomic Structure - Result Question 63

39. Which one of the following sets of quantum numbers represents an impossible arrangement?

(1986,1 M)

$n$ $l$ $m$ $s$
(a) 3 2 -2 $\frac{1}{2}$
(b) 4 0 0 $\frac{1}{2}$
(c) 3 2 -3 $\frac{1}{2}$
(d) 5 3 0 $-\frac{1}{2}$
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Answer:

Correct Answer: 39. (c)

Solution:

$ \begin{array}{llll} n & l & m & s \\ 3 & 2 & -3 & \frac{1}{2} \end{array} $

This is the wrong set of quantum number because $|m|$ cannot be greater than $l$.



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