Atomic Structure - Result Question 95

71. The maximum number of electrons that can have principal quantum number, $n=3$ and spin quantum number, $m _s=-1 / 2$, is

(2011)

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Answer:

Correct Answer: 71. $(9)$

Solution:

  1. When $n=3, l=0,1,2$ i.e. there are $3 s, 3 p$ and $3 d$-orbitals. If all these orbitals are completely occupied as

Total $18$ electrons, $9$ electrons with $s=+\dfrac{1}{2}$ and $9$ with

$ \hspace{20mm} s=-\dfrac{1}{2}$

Alternatively In any $n$th orbit, there can be a maximum of $2 n^{2}$ electrons. Hence, when $n=3$, number of maximum electrons $=$ $18$. Out of these 18 electrons, $9$ can have spin $-\dfrac{1}{2}$ and remaining nine with spin $+\dfrac{1}{2}$.



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