Extraction of Metals - Result Question 21

21. The metal that cannot be obtained by electrolysis of an aqueous solution of its salts is

(2014 Main)

(a) $Ag$

(b) $Ca$

(c) $Cu$

(d) $Cr$

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Answer:

Correct Answer: 21. (b)

Solution:

  1. Higher the position of element in the electrochemical series more difficult is the reduction of its cations.

If $Ca^{2+}(a q)$ is electrolysed, water is reduced in preference to it. Hence, it cannot be reduced electrolytically from their aqueous solution.

$ Ca^{2+}(a q)+H _2 O \longrightarrow Ca^{2+}+OH^{-}+H _2 \uparrow $



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