Extraction of Metals - Result Question 43

43. Copper is purified by electrolytic refining of blister copper. The correct statement(s) about this process is/are

(2015 Adv.)

(a) impure $Cu$ strip is used as cathode

(b) acidified aqueous $CuSO _4$ is used as electrolyte

(c) pure $Cu$ deposits at cathode

(d) impurities settle as anode-mud

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Answer:

Correct Answer: 43. (b, c, d)

Solution:

  1. (a) is wrong statement. Impure copper is set as anode where copper is oxidised to $Cu^{2+}$ and goes into electrolytic solutions.

(b) $CuSO _4$ is used as an electrolyte in purification process.

(c) Pure copper is deposited at cathode as:

$ Cu^{2+}+2 e^{-} \longrightarrow Cu: \quad \text { (At cathode) } $

(d) Less active metals like $Ag$, $Au$ etc settle down as anode mud.